On the mechanism of the photoinduced magnetism in copper octacyanomolybdates.
نویسندگان
چکیده
Ab initio calculations show that a possible mechanism for the photomagnetism in copper octacyanomolybdate compounds consists of the initial excitation of the diamagnetic Cu(II)-Mo(IV-CS) pair to a Cu(II)-Mo(IV-T) state, whose geometry relaxation stabilizes the magnetic doublet and quartet states.
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عنوان ژورنال:
- Chemical communications
دوره 46 31 شماره
صفحات -
تاریخ انتشار 2010